PHREEQC在济南泉水来源判别中的应用与效果     

徐衍兰  高宗军  李佳佳 《地下水》2015,(1):4-5

为验证济南泉域的泉水来源,选取趵突泉周围13个取样点岩溶水中的微量元素Ba和Sr,运用PHREEQC软件对这两种元素进行不同比例的混合。结果表明,济南南部山区、东郊、西郊等处的岩溶水都对趵突泉泉水有不同程度的贡献,并首次试算出各个方向来水比例。这从水化学的角度说明,趵突泉水的来源是多源的。  相似文献   

浅析高效液相色谱-质谱/质谱法测定饮用水中的灭草松和2,4-D     

周弛  王斐  郭晋君  施敏敏  李合义  吴卫东 《地下水》2015,(2)

利用高效液相色谱-质谱/质谱法,同时测定饮用水中灭草松和2,4-D,水样经0.45μm微孔滤膜过滤后直接上机,经高效液相色谱分离后,采用质谱/质谱法测定。结果表明,灭草松和2,4-D分别在0.25~8.00μg/L和1.00~30.0μg/L范围内线性良好,相关系数分别为0.9987和0.9980,检出限为0.002μg/L和0.004μg/L,相对标准偏差(RSD)分别为7.5%~8.0%和2.9%~4.8%,加标回收率分别在73.6%~90.4%和90.3%~103.0%之间。完全满足饮用水中灭草松和2,4-D的测定。  相似文献   

基于多元分析的地铁车站深基坑形变规律研究     

储灿清 《测绘》2020,43(1):35-40

鉴于深基坑变形监测中观测数据相互关联影响,结合地下管线与桩体位移等形变数据,将多元线性回归模型与灰色模型GM(1,N)应用于深基坑形变数据预测。本文根据深基坑监测基础数据进行多种形变数据的规律性分析;应用两种分析模型预测了五种基坑形变数据,将预测结果与实测值进行对比分析。结果表明,基坑监测设计合理,开挖期间形变不大、较稳定;比较两种模型,随时间生成动态参数的GM(1,N)模型具有更小的残差,能较好地预测基坑变形规律,可以用于相关项目的实施与数据分析。  相似文献   

柳珊瑚Leptogorgia rigida中甾体类成分研究     

肖细姬  邓芸  谢路凤  张琪  韦霞  于鑫  张翠仙 《热带海洋学报》2019,38(4):64-69

首次对南海柳珊瑚Leptogorgia rigida中甾体类次生代谢产物进行研究。采用硅胶柱柱层析、十八烷基硅烷键合硅胶填料、Sephadex LH-20、高效液相色谱(HPLC)及薄层色谱(TLC)等多种方法进行分离纯化, 通过核磁共振波谱(NMR)、质谱(MS)等现代波谱分析及物理常数对照等方法进行结构鉴定。从南海柳珊瑚Leptogorgia rigida次生代谢产物中分离得到8个甾类化合物, 结构依次为: 3β, 6β, 11-trihydroxy-9, 11-seco-5α-chloest-7-en-9-one (1); 3β, 6α, 11- trihydroxy-9, 11-seco-5α-chloest-7-en-9-one (2); 3β, 6α, 11-trihydroxy-5α-chloest-7, 22(E)-dien-9-one (3); pregnan-4-en-3, 20-dione (4); 5α-pregnan-3, 20-dione (5); 3β-hydroxy-pregnan-5-en-20-dion (6); 3β-hydroxy-5α-pregnan-20-one (7); 和3β, 6α, 11-trihydroxy-9, 11-seco-5α-gorgosterol (8)。所有化合物均首次从Leptogorgia属中得到。  相似文献   

Effects of dynamo magnetic fields on observational properties of accreting millisecond X-ray pulsars     

Dugasa Belay Zeleke  Solomon Belay Tessema  Seblu Humne Negu 《天文和天体物理学研究(英文版)》2021,(1)

In this paper,we have investigated accreting millisecond X-ray pulsars,which are rapidly rotating neutron stars in low-mass X-ray binaries.These systems exhibit coherent X-ray pulsations that arise when the accretion flow is magnetically channeled to the stellar surface.Here,we have developed the fundamental equations for an accretion disk around accreting millisecond X-ray pulsars in the presence of a dynamo generated magnetic field in the inner part of the disk.We have also formulated the numerical method for the structure equations in the inner region of the disk and the highest accretion rate is enough to form the inner region of the disk,which is overpowered by radiation pressure and electron scattering.Finally,we have examined our results with the effects of dynamo magnetic fields on accreting millisecond X-ray pulsars.  相似文献   

联合GPS和GRACE数据分析陕甘宁地区地表垂直形变     

郭飞霄  谷延超  崔阳  孙中苗 《大地测量与地球动力学》2020,40(7):697-703

采用甘肃省CORS网和中国大陆构造环境监测网络中共48个台站的GPS观测数据，解算得到观测台站的垂直位移，并与GRACE时变重力场Mascon模型解CSR RL05M数据计算得到的垂直形变进行比较，分析区域地表垂直形变特征。结果表明，研究区内台站垂直形变存在局部特征，甘肃庆阳和平凉地区垂直形变与其他地区存在明显差异，相关系数、均方根减少量和周年信号减少量均高于其他地区；扣除趋势项后，观测台站GPS垂直位移与GRACE垂直形变时间序列相关系数均值为0.72，GPS和GRACE周年信号振幅均值分别为6.00 mm和3.70 mm，周年信号减少量和均方根误差减少量均值分别为0.51和0.29；研究区内GPS垂直位移和GRACE垂直形变时间序列一致性较强，GRACE垂直形变能有效解释50%以上的GPS垂直位移周年信号，GPS垂直位移时间序列包含的非构造形变中平均约29%来源于环境负载变化所引起的负荷形变。  相似文献   

Formation of Li Salts from Natural Brines during Isothermal Evaporation at 25℃          下载免费PDF全文

SONG Peng-sheng  DONG Ya-ping  LI Wu 《盐湖研究》2019,27(2):1-10

Li brines are the primary resources for Li salt industries. Evaporation is necessary to concentrate Li due to its low level of concentration in raw brines. The salt sequences during the evaporation of Li brines,especially the behavior of Li salts,represent key data for solar technologies. However,chemists cannot use any phase diagram to estimate Li salt sequences during evaporation at 25℃ . The thermodynamic model proposed by us in2003 represents the only tool for the prediction of equilibrium conditions during the evaporation of solutions containing Li~+,Na~+,K~+,Mg~(2+)/Cl~-,SO_4~(2-),and-H_2 O components at 25℃ . In this paper,the predicted salt sequences of 20 brines are reported. The results indicate that( 1) the first crystallized Li salt during evaporation of Li brine varies in brine composition;( 2) lithium sulfate is crystallized in many cases initially for brines of magnesium sulfate subtype,while Db4( Li_2 SO_4·K_2 SO_4) or Db3( 2 Li_2 SO_4·Na_2 SO_4·K_2 SO_4) appears first for sodium sulfate and magnesium sulfatesubtypes with lower Mg/Li composition,and the final eutectic point is H ~+ LiC ~+ Lc ~+ Ls ~+ Car;( 3) the final eutectic point is H ~+ LiC ~+ Lc ~+ Car for brines of chloride type; and( 4) Li content corresponding to the first crystallized Li salt is in the range of 0. 43%-1%. These findings enhance our knowledge of Li chemistry and provide insights into solar pond technology of the Li-brine process.  相似文献   

The inner solar system cratering record and the evolution of impactor populations   总被引：1，自引：0，他引：1  

Robert G.Strom  Renu Malhotra  Zhi-Yong Xiao  Takashi Ito  Fumi Yoshida  Lillian R Ostrach 《天文和天体物理学研究(英文版)》2015,(3):407-434

We review previously published and newly obtained crater size-frequency distributions in the inner solar system. These data indicate that the Moon and the terrestrial planets have been bombarded by two populations of objects. Population 1,dominating at early times, had nearly the same size distribution as the present-day asteroid belt, and produced heavily cratered surfaces with a complex, multi-sloped crater size-frequency distribution. Population 2, dominating since about 3.8–3.7 Gyr,had the same size distribution as near-Earth objects(NEOs) and a much lower impact flux, and produced a crater size distribution characterized by a differential –3single-slope power law in the crater diameter range 0.02 km to 100 km. Taken together with the results from a large body of work on age-dating of lunar and meteorite samples and theoretical work in solar system dynamics, a plausible interpretation of these data is as follows. The NEO population is the source of Population 2 and it has been in near-steady state over the past ～ 3.7–3.8 Gyr; these objects are derived from the main asteroid belt by size-dependent non-gravitational effects that favor the ejection of smaller asteroids. However, Population 1 was composed of main belt asteroids ejected from their source region in a size-independent manner, possibly by means of gravitational resonance sweeping during orbit migration of giant planets;this caused the so-called Late Heavy Bombardment(LHB). The LHB began some time before ～3.9 Gyr, peaked and declined rapidly over the next ～ 100 to 300 Myr,and possibly more slowly from about 3.8–3.7 Gyr to ～2 Gyr. A third crater population(Population S) consisted of secondary impact craters that can dominate the cratering record at small diameters.  相似文献   

泉州湾表层沉积物元素特征及其地球化学意义     

官宝聪  雷怀彦  林炳煌  柳浩然  史跃中  林建宁 《台湾海峡》2010,29(1):58-65

根据2008年泉州湾调查采集的样品，测定了泉州湾表层沉积物中常量元素和微量元素的含量，采用相关分析和因子分析进行元素组合特征的研究，讨论了它们的分布趋势、相互关系和主要来源，并探讨了其地球化学意义．元素相关分析结果表明，泉州湾表层沉积物常量元素与微量元素含量的相关性明显，表层沉积物成分以SiO2和Al2O3为主，其含量的最高值分别达78．39％和22．02％（m／m），其中SiO2与大部分常量元素、微量元素的含量呈负相关，而Fe2O3、MgO、Cu、Co、Ni、Rb、Pb与Al2O3含量之间呈强正相关．元素因子分析表明，泉州湾表层沉积物的物质来源主要有陆源和生物源2种，以陆源的为主．  相似文献   

天气太热,珊瑚危险!     

莫知 《海洋世界》2010,(8):43-45

<正>在医学上,CT是一种经常被用到的技术。CT即计算机体层摄影,扫描仪利用X线对人体某一范围进行逐层的横断扫描,取得信息,然后再经由计算机处理后获得重建的图像。所获的图像为人体的横断解剖图,最终可通过计算机处理得到三维的重建图像。  相似文献